The Impact of Plasticizer Levels in Hardening PVC Plastic
Abstract
This paper provides a detailed investigation into the effects of Trioctyl Trimellitate (TOTM) plasticizer levels on the hardness of Polyvinyl Chloride (PVC) materials. The study reveals an inverse correlation between the level of TOTM plasticizer and the hardness of PVC, with an increase in TOTM levels leading to a decrease in hardness. This trend is consistent across various PVC samples, despite minor variations. The role of plasticizers in determining the physical and mechanical properties of PVC is further explored, emphasizing their function in reducing PVC’s crystallinity, thereby producing a clearer and more flexible material. This research contributes to the understanding of how plasticizers can be used to tailor the properties of PVC, leading to the development of two distinct types of PVC: Flexible PVC, which contains a plasticizer, and Rigid PVC, which does not. The findings underscore the importance of plasticizers in material design and engineering, offering valuable insights for future applications.
Downloads
References
S. Kumar, “Recent Developments of Biobased Plasticizers and Their Effect on Mechanical and Thermal Properties of Poly (vinyl chloride): A Review.,” Industrial & Engineering Chemistry Research, vol. 58, no. (27), pp. 11659–11672, 2019.
S., Mukherjee and M. Ghosh, “Performance Evaluation and Biodegradation Study of Polyvinyl Chloride Films with Castor Oil‐based Plasticizer.,” Journal of the American Oil Chemists’ Society. 2019.
A. Bodaghi, “An overview on the recent developments in reactive plasticizers in polymers.,” Polymers for Advanced Technologies., 2019.
U., Heudorf, V., Mersch-Sundermann, and J. Angerer, “Phthalates: Toxicology and exposure.,” nternational Journal of Hygiene and Environmental Health, , vol. 210`5, pp. 623–634, 2007.
Melissa Gurgel Adeodato Vieira, Mariana Altenhofen da Silva, Lucielen Oliveira dos Santos, and Marisa Masumi Beppu, “Natural-based plasticizers and biopolymer films: A review,” Eur Polym J, vol. 47, no. 3, pp. 254–263, 2011.
Rosen SL, Fundamental principles of polymeric materials. . New York: Wiley, 1993.
Jie Yu, Lushi Sun, Chuan Ma, Yu Qiao, and Hong Yao, “Thermal degradation of PVC: A review,” Waste management, vol. 48, pp. 300–314, 2016.
Z., Zhang et al., “Research progress of novel bio-based plasticizers and their applications in poly(vinyl chloride),” J Mater Sci, vol. 56, no. 17, pp. 10155–10182, 2021.
I. N., Unar, S. A. , Soomro, and S. Aziz, “Effect of Various Additives on the Physical Properties of Polyvinylchloride Resin.,” Pakistan journal of analitical and Environmental Chemistry., vol. 11, no. 2, pp. 22–50, 2010.
Allen D Godwin, “Plasticizers,” in Basic Chemicals and intermediates Technology, Texas: Exxon Chemical Company, 2000, pp. 157–175.
M., Râpă, Darie-Nita, M. R.N., and P. A. M. E., “Bio-Based Plasticizers for Polyvinylchloride (PVC).,” In: P. M., V., Darie-Nita, R.N. (eds) Polyvinylchloride-based Blends. Springer Series on Polymer and Composite Materials. Springer, 2022.
M., Bocqué, C., Voirin, V., Lapinte, S., Caillol, and J.-J. Robin, “Petro-based and bio-based plasticizers: Chemical structures to plasticizing properties.,” J Polym Sci A Polym Chem, vol. 54, no. 1, pp. 11–33, 2015.
Yogi Dhani Ermaniardo and Syamsul Hadi, “Analisis Pemlastis DOP dalam Resin PVC terhadap Kekuatan Tarik Alas Sandal Simetri,” INTEK Jurnal Penelitian., vol. 6, no. 1, pp. 8–12, 2019.
DIN EN ISO 868., “Plastics and ebonite - Determination of indentation hardness by means of a durometer (Shore hardness),” 2003.
ASTM International, “D2240 Standard Test Method for Rubber Property—Durometer Hardness.,” 2021.
(n.d), “Durometer: Pengertian, Jenis, dan Cara Kerja.” Accessed: Feb. 21, 2024. [Online]. Available: Diakses pada 21 Februari 2024, dari https://www.durometer.com/durometer-pengertian-jenis-dan-cara-kerja/
